Synthesis, Crystal Structure and Dna Binding Properties of a New Member of the [Mn3Zn2]13+ Complex Family-Reference-Cited by-同舟云学术

Synthesis, Crystal Structure and Dna Binding Properties of a New Member of the [Mn3Zn2]13+ Complex Family

Published:2012-09 Issue:9 Volume:36 Page:506-509
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Luo Yang-Hui¹,Zhou Qian¹,Sun Bai-Wang¹

Affiliation:

1. College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, P. R. China

Abstract

The complex [N(CH3)4]3[Mn3Zn2(3,5-dibromosalox)3O(N3)6Cl2] has been synthesised and characterised. It crystallises as two independent molecules and exhibits a planar [MnIII3-(μ3-oxo)] core as well as μ2-η1:η1-azide bridging geometry. DNA binding studies show that the complex binds with DNA through intercalation.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751912X13408136346284

Reference25 articles.

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3. Bidirectional Chemo-Switching of Spin State in a Microporous Framework

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