Template Effect in the Self-Assembly of a [2]Rotaxane Containing Diazapyrenium Units-Reference-Cited by-同舟云学术

Template Effect in the Self-Assembly of a [2]Rotaxane Containing Diazapyrenium Units

Published:2010-05 Issue:2 Volume:35 Page:209-217
ISSN:1468-6783
Container-title:Progress in Reaction Kinetics and Mechanism
language:en
Short-container-title:Progress in Reaction Kinetics and Mechanism

Author:

Bruschini Michele¹,Doddi Giancarlo¹,Ercolani Gianfranco²,Mencarelli Paolo¹

Affiliation:

1. Dipartimento di Chimica e CNR-IMC, Università di Roma La Sapienza, P.le Aldo Moro, 5, 00185 Roma, Italy

2. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, Via della Ricerca Scientifica, 00133 Roma, Italy

Abstract

The template effect of 1,5-Bis[2-(2-triisopropyloxyethoxy)ethoxy]naphthalene (5) on the ring closure reaction of 2-(4-Bromomethylbenzyl)-7-[4-(2,7-diazapyrenyl)-methylbenzyl]-2,7-diazapyrenium (3), to give the corresponding [2]rotaxane (7), has been quantitatively evaluated. The results are compared to those relative to the self-assembly of [2]rotaxane (8), and [2]pseudorotaxanes (9) and (10).

Publisher

SAGE Publications

Subject

Physical and Theoretical Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/146867810X12699638527777

Reference28 articles.

1. Interlocked and Intertwined Structures and Superstructures

2. Template-Directed Syntheses of Rotaxanes

3. GibsonH.W. (1996) In: SemlyenJ.A. (ed.), Large ring molecules, pp. 191–262. Wiley, New York.

4. Self-Assembly in Natural and Unnatural Systems

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1. Record Rate Enhancements for Tetrathiafulvalene Guests in the Formation of Bipyridinium- and Diazapyrenium-Based [2]Pseudorotaxanes;The Journal of Organic Chemistry;2018-08-01

2. Kinetically and thermodynamically controlled syntheses of covalent molecular capsules;Advances in Physical Organic Chemistry;2011