Rongalite®-Promoted Odourless and Highly Regioselective Synthesis of β-Hydroxyselenides under Solvent-Free Conditions-Reference-Cited by-同舟云学术

Rongalite®-Promoted Odourless and Highly Regioselective Synthesis of β-Hydroxyselenides under Solvent-Free Conditions

Published:2010-10 Issue:10 Volume:34 Page:549-552
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Lv Guangshu¹,Li Ting¹,Hu Ruijia¹,Chen Jiuxi¹,Ding Jinchang¹²,Wu Huayue¹

Affiliation:

1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China

2. Wenzhou Vocational and Technical College, Wenzhou, 325035, P. R. China

Abstract

An efficient and facile procedure for the odourless and highly regioselective synthesis of β-hydroxyselenides by the ring-opening of epoxides with 1,2-diphenyldiselenide in the presence of Rongalite® and K2CO3 under solvent-free conditions on grinding has been developed. The important features of this methodology are high yields, reasonably rapid reaction rate, simple workup, high regioselectivity and no requirement for metal catalysts.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823410X12857074253339

Reference41 articles.

1. Catalytic Applications of Chiral Organoselenium Compounds in Asymmetric Synthesis

2. Modular chiral selenium-containing oxazolines: synthesis and application in the palladium-catalyzed asymmetric allylic alkylation

3. Organoselenium and Organotellurium Compounds: Toxicology and Pharmacology

4. Diselenides and Allyl Selenides as Glutathione Peroxidase Mimetics. Remarkable Activity of Cyclic Seleninates Produced in Situ by the Oxidation of Allyl ω-Hydroxyalkyl Selenides

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