Reduction of Nitrosobenzenes to Azoarenes with Smi2-Reference-Cited by-同舟云学术

Reduction of Nitrosobenzenes to Azoarenes with Smi2

Published:2010-04 Issue:4 Volume:34 Page:214-215
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Ye Wei¹,Ding Wenbo¹,Hu Zhang²,Yu Yongping¹,Zou Hongbin¹³

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, P. R. China

2. College of Science, Guangdong Ocean University, Zhanjiang 524088, P. R. China

3. State key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, P. R. China

Abstract

A novel method was developed to synthesise azoarenes from nitrosobenzenes under mild conditions. Samarium (II) iodine was used to achieve the N–N coupling. The method also provides evidence for the proposed mechanism involved in the reduction of nitro compounds to the amines with SmI2.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823410X12706553325118

Reference16 articles.

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2. Addition, Reduction, and Oxidation Reactions of Nitrosobenzene

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4. Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent

5. Diborane Reduction of Nitro Salts. A New Synthesis of N-Monosubstituted Hydroxylamines

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1. Nitrosobenzene;Encyclopedia of Reagents for Organic Synthesis;2014-10-20

2. ChemInform Abstract: Reduction of Nitrosobenzenes to Azoarenes with SmI2.;ChemInform;2010-09-02