Acid Catalysed Reaction of Estrones with Neopentyl Glycol under Forced Conditions-Reference-Cited by-同舟云学术

Acid Catalysed Reaction of Estrones with Neopentyl Glycol under Forced Conditions

Published:2010-03 Issue:3 Volume:34 Page:158-162
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Oliveira Cristina¹,Morais Goreti Ribeiro²,Imai Masao³,Inohae Eiko³,Yamamoto Chishou³,Mataka Shuntaro⁴,Thiemann Thies³⁵

Affiliation:

1. Instituto Tecnologico e Nuclear, Estrada Nacional 10, P-2686-953 Sacavem, Portugal

2. Faculty of Pharmacy, University of Lisbon, Av. Forças Armadas, P-1649 Lisbon, Portugal

3. Interdisciplinary Graduate School of Engineering Sciences

4. Institute of Materials Chemistry and Engineering Kyushu University, 6-1, Kasuga-koh-en, Kasuga-shi 816-8580, Japan

5. Department of Chemistry, Faculty of Science, United Arab Emirates University, PO Box 17551, Al Ain, UAE

Abstract

Upon reaction with an excess of 2,2-dimethylpropane-1,3-diol (neopentyl glycol) under acid catalysis, estrones form 17-O-[2′,2′-dimethyl-2′-(5″,5″-dimethyl-1″,3″-dioxanyl)ethyl] substituted estra-3, 17β-diols. The reaction represents a formal reduction of a keto function under acidic conditions in the absence of a metal.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823410X12678785299942

Reference26 articles.

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