Synthesis of 4,16-Dimethoxy-1,2-Dimethyl[2.4]Metacyclophan-1-Ene and 8,17-Dimethoxy-1.2-Dimethyl-10-Thia[2.3.4](1,3,5)Cyclophan-1-Ene-Reference-Cited by-同舟云学术

Synthesis of 4,16-Dimethoxy-1,2-Dimethyl[2.4]Metacyclophan-1-Ene and 8,17-Dimethoxy-1.2-Dimethyl-10-Thia[2.3.4](1,3,5)Cyclophan-1-Ene

Published:2010-08 Issue:8 Volume:34 Page:445-448
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Shimizu Tomoe¹,Kato Rika¹,Miyamoto Shinpei¹,Yamato Takehiko¹

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502, Japan

Abstract

McMurry cyclisation of 1,4-bis(3-acetyl-4-methoxyphenyl)butane afforded flexible 4,16-dimethoxy-1,2-dimethyl[2.4] metacyclophan-1-ene, which was converted to the corresponding triple bridged 8,17-dimethoxy-1,2-dimethyl-10-thia[2.3.4](1,3,5)cyclophan-1-ene. The conformational studies of these cyclophan-1-enes in solution are also described.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823410X12795373456980

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