Single lithium-ion channel polymer binder for stabilizing sulfur cathodes

Author:

Niu Chaoqun1,Liu Jie1,Qian Tao1,Shen Xiaowei1,Zhou Jinqiu1,Yan Chenglin1

Affiliation:

1. College of Energy, Collaborative Innovation Center of Suzhou Nano Science and Technology, Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, China

Abstract

Abstract Lithium–sulfur batteries have great potential for high-performance energy-storage devices, yet the severe diffusion of soluble polysulfide to electrolyte greatly limits their practical applications. To address the above issues, herein we design and synthesize a novel polymer binder with single lithium-ion channels allowing fast lithium-ion transport while blocking the shuttle of unnecessary polysulfide anions. In situ UV–vis spectroscopy measurements reveal that the prepared polymer binder has effective immobilization to polysulfide intermediates. As expected, the resultant sulfur cathode achieves an excellent specific capacity of 1310 mAh g−1 at 0.2 C, high Coulombic efficiency of 99.5% at 0.5 C after 100 cycles and stable cycling performance for 300 cycles at 1 C (1 C = 1675 mA g−1). This study reports a new avenue to assemble a polymer binder with a single lithium-ion channel for solving the serious problem of energy attenuation of lithium–sulfur batteries.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Natural Science Foundation of Jiangsu Higher Education Institutions of China

Publisher

Oxford University Press (OUP)

Subject

Multidisciplinary

Reference36 articles.

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