Pliocene to Pleistocene REE-P Metasomatism in the Subcontinental Lithosphere beneath Southeast Asia—Evidence from a Monazite- and REE-rich Apatite-bearing Peridotite Xenolith from Central Vietnam

Abstract

Abstract Mantle rocks usually contain rare earth elements (REEs) in very low concentrations. Here, we document an occurrence of monazite associated with REE-rich apatites in a carbonate-bearing wehrlite xenolith from central Vietnam. The xenolith displays an equigranular matrix of rounded olivine grains while texturally primary orthopyroxene, clinopyroxene and spinel are notably absent. Scattered within the olivine matrix, two types of domains are present: domain-I contains blocky clinopyroxene grains within a matrix of quenched silicate melt and is associated with a second generation of olivine, small euhedral spinel, and rare grains of carbonates. Domain-II contains irregularly shaped patches of carbonate associated with silicate glass, secondary olivine, spinel, and clinopyroxene. Monazite and apatite occur only in domain-I: very small rounded to elongate monazite I grains are included in primary olivine, partly crosscut by fine glass veinlets, monazite II as large grains up to 300 × 200 μm in size and monazite III as small euhedral and needle-like crystals in silicate glass pools. Apatite I forms lath-shaped to rounded crystals up to 200 × 50 μm in size, whereas apatite II is present within silicate melt pools where it forms euhedral needle-like to equant grains. Monazites show compositional variation mainly with respect to ∑REE2O3 (63–69 wt %) and ThO2 (1.1–5.3 wt %) and only minor variations in P2O5 (29–32 wt %), SiO2 (<0.05–0.4 wt %), and CaO (0.2–0.4 wt %). Apatites are characterized by strongly variable and high REE2O3 and SiO2 contents (4–27 wt % ∑REE2O3, 0.6–6.8 wt % SiO2) as well as with significant Na2O (0.3–1.5 wt %), FeO (0.1–1.8 wt %), MgO (0.2–0.6 wt %) and SrO (0.2–0.9 wt %) contents. F and Cl contents are in the range 1.9–3.0 wt % and 0.2–0.8 wt %, respectively. The textures observed in this wehrlite xenolith are thought to be the result of an interaction of depleted (harzburgitic) mantle with cogenetic silicate and carbonatite melts formed by fractionation-driven immiscibility within a parental SiO2 undersaturated melt characterized by high P, CO2, and REE contents. The immiscibility occurred in the shallow subcontinental lithosphere at T of 700–800 °C and a depth of ~30 km and the melt–rock interaction occurred in two successive and most likely nearly simultaneous events: an initial stage of metasomatism was triggered by the P-REE-CO2-rich agent with low aH2O resulting in the co-precipitation of carbonates as patches and along micro-veins and of phosphates in a peridotitic assemblage. A second stage is characterized by pervasive infiltration of an alkali-rich basaltic melt into the carbonate + phosphate-bearing assemblage. Based on 232Th and 208Pb contents of monazite, a young age of ~2 Ma can be calculated for the timing of the monazite-forming metasomatic imprint. Based on 39Ar-40Ar extrusion ages of the xenolith-hosting alkali basalts of 2.6–5.4 Ma, this indicates that both carbonatite and basaltic melt infiltration must have occurred no more than a few hundred thousand years before extraction of the xenolith to the surface.