Spectroscopy

Author:

Nitzan Abraham12

Affiliation:

1. University of Pennsylvania , Philadelphia, PA, USA

2. Tel Aviv University , Tel Aviv, Israel

Abstract

Abstract This chapter focuses on spectroscopic applications of time dependent quantum mechanics focusing on molecular spectroscopy in condensed phases. (1) Molecular spectroscopy in the dressed state picture. (2) Resonance Raman scattering. (3) Resonance energy transfer. (4) Collective excitation and emission. (5) Thermal relaxation and dephasing (the Bloch equations, relaxation of a prepared state, dephasing (decoherence), the absorption lineshape, homogeneous and inhomogeneous broadening, motional narrowing, thermal effects in resonance Raman scattering). (6) A case study: Resonance Raman scattering and fluorescence from Azulene in a Naphthalene matrix. (7) Probing inhomogeneous bands (hole-burning spectroscopy, photon echoes, single-molecule spectroscopy. (8) Optical response functions.

Publisher

Oxford University PressOxford

Reference11 articles.

1. Intermolecular Energy Migration and Fluorescence;Förster;Ann. Phys.,1948

2. Long Range Resonance Energy Transfer in Molecular Systems;Scholes;Annu. Rev. Phys. Chem,2003

3. Single-Molecule Fluorescence Resonance Energy Transfer;Ha;Methods,2001

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