Dual-layer cocatalysts of Co–Pi and Ni(OH)2 on BiVO4 photoanodes for efficient water oxidation

Author:

Zhang Yu1,Guo Peng1,Tang Yonghua1,Li Hongxing1,Mo Rong1

Affiliation:

1. Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, School of Physics and Optoelectronics, Xiangtan University , Yanggutang street, Yuhu District, xiangtan, Hunan Province, 411105 , China

Abstract

Abstract Slow oxygen evolution kinetics and severe corrosion limit the further application of BiVO4 photoelectrodes in photoelectrochemical water splitting. Here, BiVO4/Co–Pi/Ni(OH)2 photoanodes were synthetized with the aim of improving their photoelectric conversion efficiency and stability. Compared with a pure BiVO4 photoanode, the BiVO4/Co–Pi/Ni(OH)2 photoanode enhanced the photocurrent from 1.1 to 4.5 mA/cm2 at 1.23 V versus the reversible hydrogen electrode. In addition, Ni(OH)2 acted as a corrosion protection layer on the surface of the photoanode, allowing the BiVO4/Co–Pi/Ni(OH)2 photoanode to exhibit excellent stability.

Funder

Scientific Research Foundation of Hunan Provincial Education Department

Publisher

Oxford University Press (OUP)

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