Affiliation:
1. Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University , 1-4-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8527 , Japan
Abstract
Abstract
Lacunary polyoxometalates represent a distinctive category of inorganic multidentate ligands that serve as precursors for building organic–inorganic hybrid materials and multinuclear metal oxo clusters. In this study, we successfully synthesized and characterized the organic–inorganic hybrid, [P2W12O44(C6H5PO3)2]10−. Two phenylphosphonato ligands were introduced at both ends of the vacant site to form the unique organic–inorganic–organic structure.
Funder
JSPS KAKENHI
MEXT Leading Initiative for Excellent Young Researchers
JST PRESTO
Toyota Riken Scholar Program
JSPS KAKENHI Grant-in-Aid for Transformative Research Area (A) “Supra-ceramics”
JSPS Core-to-Core Program
Publisher
Oxford University Press (OUP)