On-surface smooth polymerization of 5,11-bianthryl-anthradithiophene

Author:

Kasahara Shoma1,Ohtomo Manabu2,Hayashi Ryunosuke1,Fushimi Naoki2,Yamaguchi Junichi2,Matsuo Kyohei1,Aratani Naoki1,Sato Shintaro2,Hayashi Hironobu1,Yamada Hiroko1

Affiliation:

1. Division of Materials Science, Nara Institute of Science and Technology , 8916-5 Takayama-cho , Ikoma, Nara 630-0192, Japan

2. Fujitsu Research, Fujitsu Limited , 10-1 Morinosato-Wakamiya , Atsugi, Kanagawa 243-0197, Japan

Abstract

Abstract An anthracene trimer comprising an anthradithiophene central unit has been successfully synthesized and its structure was confirmed by using single-crystal X-ray analysis. The surface-assisted reaction of the trimer on Au(111) under ultra-high vacuum conditions provided a long 5,11-bianthryl-anthradithiophene polymer with its length of more than 90 nm, owing to the efficient diffusion of the trimer on the Au(111) surface.

Funder

JST CREST

JST PRESTO

Grants-in-Aid for Scientific Research

Publisher

Oxford University Press (OUP)

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