Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments-Reference-Cited by-同舟云学术

Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments

Published:2023-12-01 Issue:1 Volume:53 Page:
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:

Author:

Dumartin Melissa¹,Abid Seifallah¹,Gisbert Yohan¹,Saffon-Merceron Nathalie²,Gao Sheng³,Armaroli Nicola³,Ventura Barbara³,Kammerer Claire¹,Rapenne Gwénaël¹⁴

Affiliation:

1. CEMES, Université de Toulouse, CNRS , 29 rue Marvig, F-31055 Toulouse Cedex 4 , France

2. Université de Toulouse, UPS, ICT UAR2599 , 118 route de Narbonne , F-31062 Toulouse, France

3. Istituto per la Sintesi Organica e la Fotoreattività, CNR-ISOF , Via Gobetti 101 , 40129 Bologna, Italy

4. Division of Materials Science, Nara Institute of Science and Technology, NAIST , 8916-5 Takayama-cho , Ikoma, Nara 630-0192, Japan

Abstract

Abstract We synthesised star-shaped ruthenium(II) complexes containing one or five styryl-BODIPY units arranged around a central trisindazolylrutheniumcyclopentadienyl fragment. A symmetric complex was obtained following a five-fold Suzuki-Miyaura reaction of the pentabrominated key precursor while desymmetrisation was next achieved via a modular synthetic approach based on sequential chemoselective Suzuki-Miyaura reactions on a key building block bearing one iodophenyl and four bromophenyl groups.

Funder

JSPS KAKENHI

Publisher

Oxford University Press (OUP)

Link

https://academic.oup.com/chemlett/advance-article-pdf/doi/10.1093/chemle/upad003/53971862/upad003.pdf

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