Synthesis, characterization, and OFET characteristics of p-type organic semiconductors incorporating diketopyrrolopyrrole and thiadiazole-quinoxaline acceptors

Author:

Takahashi Naohiro1,Nishiyama Tomoki1,Weng Weichun1,Miwa Yuki1,Marumoto Shinsuke2,Kitoh-Nishioka Hirotaka3ORCID,Tanaka Senku34,Okubo Takashi34

Affiliation:

1. Department of Chemistry, Kindai University , 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502 , Japan

2. Joint Research Center, Kindai University , 3-4-1 Kowakae, Higashi-osaka, Osaka 577-8502 , Japan

3. Department of Energy and Materials, Kindai University , 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502 , Japan

4. Research Institute of Science and Technology, Kindai University , 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502 , Japan

Abstract

Abstract P-type Organic Semiconductors, TQx5-BT-DPP8 (1a) and TQx5-BT-DPP20 (1b), consisting of a donor unit of bithiophene (BT) and two acceptor units of thiadiazole quinoxaline (TQx) and diketopyrrolopyrrole (DPP), were synthesized, and their electronic states and physical properties were elucidated. These semiconductors demonstrate strong absorption extending from the visible to the near-infrared region, functioning effectively as strong donor dyes. The organic field-effect transistors (OFETs) exhibited normally on transistor characteristics, with carrier mobilities of 1.1 × 10−3 cm2/Vs for 1a and 3.3 × 10−4 cm2/Vs for 1b.

Funder

JKA

KEIRIN RACE

2021 Kindai University Research Enchancement

Publisher

Oxford University Press (OUP)

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