Reversible mechanoresponsive luminescence based on an unsymmetrical D-π-A type phenanthroimidazole derivative

Author:

Xie Xide1,Luo Bingbing2,Sun Yue2,Duan Lian2,Chen Shuwei2,Li Jie3

Affiliation:

1. College of Chemical Engineering and Technology, Taiyuan University of Technology , No. 79 Yingze West Street, Taiyuan 030-024 , China

2. College of Chemistry, Taiyuan University of Technology , No. 79 Yingze West Street, Taiyuan 030-024 , China

3. Ministry of Education Key Laboratory of Interface Science and Engineering in Advanced Materials, Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology , No. 79 Yingze West Street, Taiyuan 030-024 , China

Abstract

Abstract A kind of D-π-A mechanoresponsive luminescent molecule 2- (4- (1H-phenanthro[9,10-d] imidazol) benzylidene) malononitrile (ANPPI) was synthesized and characterized by UV absorption, photoluminescence, and other techniques. The obvious mechanoresponsive properties of ANPPI were reversible upon grinding and fuming, and were demonstrated by X-ray diffraction, scanning electron microscopy, and differential scanning calorimetry.

Funder

Natural Science Foundation of Shanxi Province

Publisher

Oxford University Press (OUP)

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