Alterations in magnetic properties of crystals of trinuclear copper complexes: isolated entities versus one-dimensional chains

Author:

Hosoya Yosuke1ORCID,Yoshikawa Hiroki1,Tsukamoto Arata1,Sugawa Kosuke1,Otsuki Joe1

Affiliation:

1. College of Science and Technology, Nihon University , 1-8-14 Kanda Surugadai , Chiyoda-ku, Tokyo 101-8308, Japan

Abstract

Abstract We obtained two types of crystals of a complex under different crystallization conditions, each exhibiting distinct molecular arrangements and magnetic interactions: one type consists of isolated complexes, while the other forms one-dimensional chains without extra bridging ligands. This approach provides a new avenue for tuning the magnetic properties of metal-complex-based materials.

Funder

Kakenhi

Japan and Advanced Research Infrastructure for Materials and Nanotechnology in Japan

Publisher

Oxford University Press (OUP)

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