Inhibitory effect of acetyl-CoA on a visible light–driven NADH regeneration system composed a of water-soluble zinc porphyrin and a rhodium complex

Author:

Takeuchi Mika1,Amao Yutaka12ORCID

Affiliation:

1. Graduate School of Science, Osaka Metropolitan University , Sugimoto, Sumiyoshi-ku , Osaka 558-8585, Japan

2. Research Centre for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University , Sugimoto, Sumiyoshi-ku , Osaka 558-8585, Japan

Abstract

Abstract Acetyl-CoA was found to act as an inhibitor of reduced nicotinamide adenine dinucleotide (NADH) production by a visible light redox system consisting of a water-soluble zinc porphyrin, Zn tetrakis(4-N,N,N-trimethylaminophenyl)porphyrin, and a rhodium complex [Cp*Rh(bpy)(H2O)]2+ (Cp* = pentamethylcyclopentadienyl, bpy = 2,2′-bipyridyl).

Funder

Grant-in-Aid for Specially promoted Research

Scientific Research

Joint International Research (Fostering Joint International Research

Institute for Fermentation, Osaka

Publisher

Oxford University Press (OUP)

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