A fast crystallization of TUN zeolite via the interzeolite conversion method

Author:

Lu Yao1,Qin Feiyu1,Wang Yong1,Simancas Raquel2,Cai Yibing1,Kondo Junko N1,Gies Hermann13,Yokoi Toshiyuki14

Affiliation:

1. Institute of Innovative Research, Tokyo Institute of Technology , 4259 Nagatsuta, Midori-ku , Yokohama, Kanagawa 226-8501, Japan

2. Institute of Engineering Innovation, School of Engineering, The University of Tokyo , 2-11-16 Yayoi, 16 Bunkyo-ku , Tokyo 113-8656, Japan

3. Institute of Geology, Mineralogy und Geophysics, Ruhr-University Bochum , Bochum 44780   Germany

4. iPEACE223 Inc. , Konwa Building, 1-12-22 Tsukiji, Chuo-ku , Tokyo 104-0045, Japan

Abstract

Abstract A TUN-type aluminosilicate zeolite was rapidly synthesized via the interzeolite conversion method (IZC) using a MWW-type one as a starting material. It was found that the co-addition of the organic structure direct agent (OSDA) and the seed played a crucial role in accelerating the crystallization of the TUN phase. The TUN zeolite synthesized via the IZC method exhibited comparable physicochemical properties to those of the conventional one crystallized from amorphous silica and alumina materials.

Funder

JSPS KAKENHI Grant-in-Aid for Scientific Research

Publisher

Oxford University Press (OUP)

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