Synthesis and biodegradation of atactic polymer based on 3-hydroxybutanoic acid-Reference-Cited by-同舟云学术

Synthesis and biodegradation of atactic polymer based on 3-hydroxybutanoic acid

Published:2024-02-27 Issue:3 Volume:53 Page:
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:

Author:

Yokaryo Hiroto¹,Nakayama Atsuyoshi²,Kawasaki Norioki²,Yamano Naoko²,Ida Sayuri²,Tokiwa Yutaka²

Affiliation:

1. Environment and Resources Group, Okinawa Industrial Technology Center , 12-2 Suzaki, Uruma, Okinawa 904-2234 , Japan

2. Biomedical Research Institute,National Institute of Advanced Industrial Science and Technology (AIST) , 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577 , Japan

Abstract

Abstract Atactic poly[(R,S)-3-hydroxybutanoic acid] with varying enantiomer ratios was synthesized using a combination of renewable (R)-3-hydroxybutanoic acid and its racemic mixture. The melting temperature of the synthesized atactic polymers was consistently lower than that of poly[(R)-3-hydroxybutanoic acid], exhibiting a decreasing trend with an increasing enantiomer ratio. The biodegradability of the synthesized polymers was assessed through enzymatic and seawater degradation studies.

Publisher

Oxford University Press (OUP)

Link

https://academic.oup.com/chemlett/advance-article-pdf/doi/10.1093/chemle/upae038/56774148/upae038.pdf

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