Chemical Analysis for Alkali Ion–exchanged Glass Using Atom Probe Tomography

Abstract

Abstract The developing flexible ultrathin glass for use in foldable displays has attracted widespread attention as an alternative to rigid electronic smartphones. However, the detailed compositional effects of chemically strengthened glass are not well understood. Moreover, the spatially resolved chemistry and depth of the compression layer of tempered glass are far from clear. In this study, commonly used X-ray spectroscopy techniques and atom probe tomography (APT) were used comparatively to investigate the distribution of constituent elements in two representative smartphone glass samples: non- and chemically tempered. APT has enabled sub-nanoscale analyses of alkali metals (Li, Na, K, and Ca) and this demonstrates that APT can be considered as an alternative technique for imaging the chemical distribution in glass for mobile applications.