Methanol and glycolaldehyde production from formaldehyde in massive star-forming regions

Author:

Silva Silvia G S1,Vichietti Rafael M2,Haiduke Roberto L A3,Machado Francisco B C2ORCID,Spada Rene F K4ORCID

Affiliation:

1. Departamente de Física, Universidade Federal do Espírito Santo, Vítória, 29.075-910 Espírito Santo, Brazil

2. Departamento de Química, Instituto Tecnológico de Aeronáutica, São José dos Campos, 12.228-900 São Paulo, Brazil

3. Departamento de Química e Física Molecular, Instituto de Química de São Carlos, Universidade de São Paulo, São Carlos, 13560-970 São Paulo, Brazil

4. Departamento de Física, Instituto Tecnológico de Aeronáutica, São José dos Campos, 12.228-900 São Paulo, Brazil

Abstract

ABSTRACT Based on typical physical and chemical conditions expected in massive and dense hot cores during the protostar collapse, the formation of glycolaldehyde (CH2OHCHO) and methanol (CH3OH) was investigated from H2 and CO and formaldehyde (H2CO) as an intermediate. Thermochemical properties and rate constants were obtained for gas-phase reactions using high-level electronic structure methods and chemical kinetic calculations, and the concentrations of the molecules were evolved along time. The chemical equilibrium was reached in minutes at 1500 K, a time interval much shorter than that required time for a protostar formation process. The results indicate that the formaldehyde and methanol abundances are always larger than those for glycolaldehyde, for example, at 2000 K and [H2]0 equals to 1023 molecule cm−3, the abundances of H2CO, CH3OH, and CH2OHCHO relative to H2 are equal to 3 × 10−6, 5 × 10−6, and 1 × 10−12, while for [H2]0 equals to 1020 molecule cm−3  these abundances are 3 × 10−9, 5 × 10−12, and 2 × 10−21, respectively. Considering that our results can be applied to explain the proximity of methanol and formaldehyde maser emissions, from the whole set of results, the CH3OH abundance relative to H2CO ranges from 10−3 to 102.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Oxford University Press (OUP)

Subject

Space and Planetary Science,Astronomy and Astrophysics

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3