Affiliation:
1. National Institute of Clean-and-Low-Carbon Energy, Future Science & Technology City, Changping District, Beijing, China
Abstract
AbstractDevelopment of new power anode material with both high capacity and high-rate capability for lithium-ion batteries is highly desired. In this paper, a novel soft carbon anode for rechargeable lithium-ion batteries was developed using coal-based mesophase pitch. The structures of the materials were characterized by X-ray diffraction (XRD), Raman, N2 adsorption–desorption, Scanning Electron Microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The electrochemical characteristics of the new anode material were investigated. It was found that the soft carbon anode from coal-based mesophase pitch carbonized under vacuum conditions can deliver higher energy density and higher rate capability compared to soft carbon carbonized under a nitrogen atmosphere. The enhanced electrochemical properties are attributed to smaller nanocrystallites, more porosity, defects and carbon species of the resulting anode material.
Publisher
Oxford University Press (OUP)
Subject
Management, Monitoring, Policy and Law,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Environmental Engineering
Reference26 articles.
1. Fundamental scientific aspects of lithium batteries (VIII)—anode electrode materials;Luo;Energy Storage Sci Technol,2014
2. Carbonaceous anode materials for lithium-ion batteries—the road ahead;Kumar;J Indian I Sci,2009
3. Carbon surface functionalities and SEI formation during Li intercalation;Collins;Carbon,2015
4. Crystallite growth in graphitizing and non-graphitizing carbons;Franklin;Proc Roy Soc Lond A,1951
5. Determination of the lithium ion diffusion coefficient in graphite anode material;Tang;Acta Phys–Chim Sin,2001
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