Tuning 2D magnetism in Fe3+XGeTe2 films by element doping

Author:

Liu Shanshan12,Li Zihan12,Yang Ke13,Zhang Enze12,Narayan Awadhesh4,Zhang Xiaoqian5,Zhu Jiayi6,Liu Wenqing7,Liao Zhiming89,Kudo Masaki10,Toriyama Takaaki10,Yang Yunkun12,Li Qiang12,Ai Linfeng12,Huang Ce12,Sun Jiabao7,Guo Xiaojiao11,Bao Wenzhong11,Deng Qingsong9,Chen Yanhui9,Yin Lifeng1212,Shen Jian1212,Han Xiaodong9,Matsumura Syo1013,Zou Jin814,Xu Yongbing5,Xu Xiaodong6,Wu Hua1312,Xiu Faxian121215ORCID

Affiliation:

1. State Key Laboratory of Surface Physics and Department of Physics, Fudan University, Shanghai 200433, China

2. Institute for Nanoelectronic Devices and Quantum Computing, Fudan University, Shanghai 200433, China

3. Laboratory for Computational Physical Sciences (MOE), Fudan University, Shanghai 200433, China

4. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India

5. School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China

6. Department of Physics, University of Washington, Seattle, WA 98195-1560, USA

7. Department of Electronic Engineering, Royal Holloway University of London, Egham TW20 0EX, UK

8. Materials Engineering, The University of Queensland, Brisbane QLD 4072, Australia

9. Beijing Key Lab of Microstructure and Property of Advanced Material, Institute of Microstructure and Properties of Advanced Materials, Beijing University of Technology, Beijing 100124, China

10. The Ultramicroscopy Research Center, Kyushu University, Fukuoka 819-0395, Japan

11. State Key Laboratory of ASIC and System, School of Microelectronics, Fudan University, Shanghai 200433, China

12. Collaborative Innovation Center of Advanced Microstructures, Nanjing 210093, China

13. Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoka 819-0395, Japan

14. Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane QLD 4072, Australia

15. Shanghai Research Center for Quantum Sciences, Shanghai 201315, China

Abstract

Abstract Two-dimensional (2D) ferromagnetic materials have been discovered with tunable magnetism and orbital-driven nodal-line features. Controlling the 2D magnetism in exfoliated nanoflakes via electric/magnetic fields enables the boosted Curie temperature (TC) or phase transitions. One of the challenges, however, is the realization of high TC 2D magnets that are tunable, robust and suitable for large scale fabrication. Here, we report molecular-beam epitaxy growth of wafer-scale Fe3+XGeTe2 films with TC above-room-temperature. By controlling the Fe composition in Fe3+XGeTe2, a continuously-modulated TC in a broad range of 185–320 K has been achieved. This widely tunable TC is attributed to the doped interlayer Fe that provide a 40% enhancement around the optimal composition X = 2. We further fabricated magnetic tunneling junction device arrays that exhibit clear tunneling signals. Our results show an effective and reliable approach, i.e. element doping, to produce robust and tunable ferromagnetism beyond room temperature in a large-scale 2D Fe3+XGeTe2 fashion.

Publisher

Oxford University Press (OUP)

Subject

Multidisciplinary

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