Use of water isotopes and chemistry to infer the type and degree of exchange between groundwater and lakes in an esker complex of northeastern Ontario, Canada

Abstract

Abstract. While interactions between groundwater and lake-water influence water chemistry, water balance, aquatic organisms, biochemical cycles and contamination levels, they remain a poorly studied component of lake hydrology. Identifying the controls of groundwater and lake-water interactions at the landscape level and classifying lakes into categories based on their degree of interaction with the groundwater can provide insights into a lake's sensitivity and vulnerability to environmental stressors. Such information can also provide baseline conditions for comparison to future changes that are important for water management and conservation. To this end, water chemistry and water isotopic composition were investigated in a set of 50 boreal lakes located at different elevations in an esker system near Timmins, Ontario. Analyses focused on stable isotopic ratios of hydrogen and oxygen and specific conductance as indicators of the position of a lake with respect to the influence of groundwater. Both isotopic composition and specific conductance distinguished higher-elevation groundwater-recharge lakes from lower-elevation groundwater-discharge lakes. Groundwater-recharge lakes were high-elevation lakes characterized by enriched isotopic values and low values of specific conductance. In contrast, groundwater-discharge lakes were isotopically depleted and had higher values of specific conductance and occurred at lower elevations. An intermediate group of lakes was also defined (termed seepage lakes) and had intermediate isotopic and water-chemistry characteristics compared to recharge and discharge lakes. Differences in water geochemistry between field campaigns revealed that upland groundwater-recharge lakes showed evidence of evaporative drawdown, indicating sensitivity to short-term changes in climate, whereas the lower-elevation groundwater-discharge lakes showed little variation between seasonal samples and consequently would likely be affected only by hydroclimatological changes of greater duration and magnitude.