Analysis of Event-based Hydrological Processes at the Hydrohill Catchment Using Hydrochemical and Isotopic Methods

Abstract

Abstract. Hydrochemical and isotopic techniques have been widely applied in hydrological sciences because isotopic tracers can identify water sources and hydrochemical tracers can discern runoff flow paths. To better understand the hydrological process, we combined hydrochemical and isotopic techniques under controlled experimental conditions to investigate hydrological process from rainfall to runoff in the Hydrohill experiment catchment, a typical artificial catchment in Chuzhou, China. Hydrochemical and isotopic data, i.e., pH, electric conductivity (EC), total dissolved solids (TDS), anions (Cl−, NO3-, SO42- and HCO3-), cations (K+, Na+, Ca2+ and Mg2+) and dissolved Si, 18O and D in water samples were collected during a rainfall event in 2016, and used to determine the hydrochemical and isotopic characteristics of rainfall and runoff components. We applied EC, TDS, SO42-, Ca2+, Mg2+, 18O and D as tracers to investigate rainfall-runoff processes in the experimental catchment. Runoff flow paths could be well identified by the relationship between 18O and EC, TDS, SO42-, Ca2+ and Mg2+. The quantity of flow flux and mass fluxes of main hydrochemical and isotopic tracers gauged at the catchment outlet shows applicable tracers (Ca2+, Mg2+, SO42-, and 18O) are mainly from deep groundwater runoff (from soil layer of 60–100 cm beneath ground surface). Contributions of the event water and pre-event water to the total runoff during the rainfall-runoff process are different. The quantitative results were very encouraging as a basis to develop hydrological models for further study.