MAX-DOAS formaldehyde slant column measurements during CINDI: intercomparison and analysis improvement
-
Published:2013-01-31
Issue:1
Volume:6
Page:167-185
-
ISSN:1867-8548
-
Container-title:Atmospheric Measurement Techniques
-
language:en
-
Short-container-title:Atmos. Meas. Tech.
Author:
Pinardi G.ORCID, Van Roozendael M., Abuhassan N., Adams C., Cede A., Clémer K., Fayt C., Frieß U.ORCID, Gil M., Herman J.ORCID, Hermans C., Hendrick F., Irie H., Merlaud A., Navarro Comas M., Peters E., Piters A. J. M., Puentedura O.ORCID, Richter A.ORCID, Schönhardt A., Shaiganfar R., Spinei E., Strong K.ORCID, Takashima H., Vrekoussis M.ORCID, Wagner T., Wittrock F., Yilmaz S.
Abstract
Abstract. We present intercomparison results for formaldehyde (HCHO) slant column measurements performed during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI) that took place in Cabauw, the Netherlands, in summer 2009. During two months, nine atmospheric research groups simultaneously operated MAX-DOAS (MultiAXis Differential Optical Absorption Spectroscopy) instruments of various designs to record UV-visible spectra of scattered sunlight at different elevation angles that were analysed using common retrieval settings. The resulting HCHO data set was found to be highly consistent, the mean difference between instruments generally not exceeding 15% or 7.5 × 1015 molec cm−2, for all viewing elevation angles. Furthermore, a sensitivity analysis was performed to investigate the uncertainties in the HCHO slant column retrieval when varying key input parameters such as the molecular absorption cross sections, correction terms for the Ring effect or the width and position of the fitting interval. This study led to the identification of potentially important sources of errors associated with cross-correlation effects involving the Ring effect, O4, HCHO and BrO cross sections and the DOAS closure polynomial. As a result, a set of updated recommendations was formulated for HCHO slant column retrieval in the 336.5–359 nm wavelength range. To conclude, an error budget is proposed which distinguishes between systematic and random uncertainties. The total systematic error is estimated to be of the order of 20% and is dominated by uncertainties in absorption cross sections and related spectral cross-correlation effects. For a typical integration time of one minute, random uncertainties range between 5 and 30%, depending on the noise level of individual instruments.
Publisher
Copernicus GmbH
Subject
Atmospheric Science
Reference78 articles.
1. Aliwell, S. R., Van Roozendael, M., Johnston, P. V., Richter, A., Wagner, T., Arlander, D. W., Burrows, J. P., Fish, D. J., Jones, R. L., Tørnkvist, K. K., Lambert, J.-C., Pfeilsticker, K., and Pundt, I.: Analysis for BrO in zenith-sky spectra: An intercomparison exercise for analysis improvement, J. Geophys. Res., 107, D140, https://doi.org/10.1029/2001JD000329, 2002. 2. Bobrowski, N., Hönninger, G., Galle, B., and Platt, U.: Detection of bromine monoxide in a volcanic plume, Nature, 423, 273–276, https://doi.org/10.1038/nature01625, 2003. 3. Bogumil, K., Orphal, J., Homann, T., Voigt, S., Spietz, P., Fleischmann, O. C., Vogel, A., Hartmann, M., Bovensmann, H., Frerik, J., and Burrows, J. P.: Measurements of molecular absorption spectra with the SCIAMACHY Pre-Flight Model: Instrument characterization and reference spectra for atmospheric remote sensing in the 230–2380 nm region, J. Photochem. Photobiol. A, 157, 167–184, 2003. 4. Brinksma, E. J., Pinardi, G., Volten, H., Braak, R., Richter, A., Schoenhardt, A., Van Roozendael, M., Fayt, C., Hermans, C., Dirksen, R. J., Vlemmix, T., Berkhout, A. J. C., Swart, D. P. J., Oetjes, H., Wittrock, F., Wagner, T., Ibrahim, O., de Leeuw, G., Moerman, M., Curier, R. L., Celarier, E. A., Cede, A., Knap, W. H., Veefkind, J. P., Eskes, H. J., Allaart, M., Rothe, R., Piters, A. J. M., and Levelt, P. F.: The 2005 and 2006 DANDELIONS NO2 and aerosol intercomparison campaigns, J. Geophys. Res., 113, D16S46, https://doi.org/10.1029/2007JD008988, 2008. 5. Burrows, J. P., Dehn, A., Deters, B., Himmelmann, S., Richter, A., Voigt, S., and Orphal, J.: Atmospheric remote-sensing reference data from GOME: Part 1. Temperature-dependent absorption cross-sections of NO2 in the 231–794 nm range, J. Quant. Spectrosc. Ra., 60, 1025–1031, 1998.
Cited by
77 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
|
|