An evaluation of ambient ammonia concentrations over southern Ontario simulated with different dry deposition schemes within STILT-Chem v0.8

Abstract

Abstract. A bi-directional air-surface exchange scheme for atmospheric ammonia was incorporated into the Stochastic Time-Inverted Lagrangian Transport air quality model (STILT-Chem v0.8). STILT-Chem v0.8 was then applied to simulate atmospheric ammonia concentrations at 53 measurement sites in the province of Ontario, Canada for a six-month period from 1 June to 30 November 2006. In addition to the bi-directional scheme, two uni-directional dry deposition schemes were tested. Comparisons of modeled ammonia concentrations against observations show that all three schemes can reasonably predict observations. For sites with low observed ammonia concentrations, the bi-directional scheme clearly overestimated ammonia concentrations. Although all three schemes tend to underestimate ammonia concentrations for locations with elevated observed concentrations, the bi-directional scheme performed better due mainly to its introduction of compensation points into flux calculation parameterizations. The results of additional sensitivity tests suggest that uncertainties in the input values of emission potentials in the bi-directional scheme greatly affect the accuracy of modeled ammonia concentrations. The use of much larger emission potentials than provided in the scheme is required for accurate prediction of elevated ammonia concentrations at intensive agricultural locations.