Ventilation of the Mediterranean Sea constrained by multiple transient tracer measurements

Abstract

Abstract. Ventilation is the prime pathway for ocean surface perturbations, such as temperature anomalies, to be relayed to the ocean interior. It is also the conduit for gas exchange between atmosphere and ocean and thus the mechanism whereby, for instance, the interior ocean is oxygenated and enriched in anthropogenic carbon. The ventilation of the Mediterranean Sea is fast in comparison to the world ocean and has large temporal variability, so that quantification of Mediterranean Sea ventilation rates is challenging and very relevant for Mediterranean oceanography and biogeochemistry. Here we present transient tracer data from a field-campaign in April 2011 that sampled a unique suite of transient tracers (SF6, CFC-12, tritium and 3He) in all major basins of the Mediterranean. We apply the Transit Time Distribution (TTD) model to the data which then constrain the mean age, the ratio of the advective/diffusive transport mechanism, and the presence, or not, of more than one significant (for ventilation) water mass. We find that the eastern part of the Eastern Mediterranean can be reasonable described with a one dimensional Inverse Gaussian (1IG) TTD, and thus constrained with two independent tracers. The ventilation of the Ionian Sea and the Western Mediterranean can only be constrained by a multidimensional TTD. We approximate the ventilation with a two-dimensional Inverse Gaussian (2IG) TTD for these areas and demonstrate one way of constraining a 2IG-TTD from the available transient tracer data. The deep water in the Ionian Sea has higher mean ages than the deep water of the Levantine Basin despite higher transient tracer concentrations. This is partly due to the deep water of Adriatic origin having more diffusive properties in the transport and formation, i.e. a high ratio of diffusion over advection, compared to the deep water of Aegean Sea origin that still dominates the deep Levantine Basin deep water after the Eastern Mediterranean Transient (EMT) in the early 1990s. We also show that the deep Western Mediterranean has approximately 40% contribution of recently ventilated deep water from the Western Mediterranean Transition (WMT) event of the mid-2000s. The deep water has higher transient tracer concentrations than the mid-depth water, but the mean age is similar.