Measurement report: Characterisation and sources of the secondary organic carbon in a Chinese megacity over 5 years from 2016 to 2020
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Published:2022-09-30
Issue:19
Volume:22
Page:12789-12802
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ISSN:1680-7324
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Container-title:Atmospheric Chemistry and Physics
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language:en
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Short-container-title:Atmos. Chem. Phys.
Author:
Wang Meng, Duan Yusen, Xu WeiORCID, Wang Qiyuan, Zhang Zhuozhi, Yuan Qi, Li Xinwei, Han Shuwen, Tong HaijieORCID, Huo Juntao, Chen Jia, Gao Shan, Wu Zhongbiao, Cui Long, Huang Yu, Xiu Guangli, Cao Junji, Fu QingyanORCID, Lee Shun-cheng
Abstract
Abstract. To investigate impact factors and source area of secondary organic aerosols
in the Yangtze River Delta (YRD) region, a world-class urban agglomeration
in China, long-term measurements of organic carbon (OC) and elementary
carbon (EC) in particulate matter of less than 2.5 µm (PM2.5) with
hourly time resolution were conducted at a regional site in Shanghai from
2016 to 2020. Based on the 5-year measurements, the interannual, monthly,
seasonal, and diurnal variations in OC and EC, as well as OC subtypes, i.e.
secondary OC (SOC) and primary OC (POC), apportioned by the novel
statistical model of the minimum R2 method, and the formation pathways
of SOC, are presented. By examining the relationship between SOC and
temperature, as well as relative humidity (RH), we show that SOC formation
is greatly enhanced at high temperatures (> 30 ∘C), whereas it
correlates inversely with RH. In particular, we show that the
photochemical formation of SOC is the major formation pathway even in winter,
when solar radiation was supposedly less intense than in summer, which is
different from that in the north China plain, where aqueous phase chemistry is
found to be an important SOC formation pathway. Moreover, increased SOC
concentrations are also found to be associated with high wind speed
(> 5 m s−1) in winter, which is increased by 29.1 % (2.62
µg m−3) when compared with that during lower winds, suggesting
regional sources of SOC in winter. By analysing the potential source regions
using the concentration-weighted trajectory (CWT), the geographic regions of
SOC are found to be mainly associated with transport from outside Shanghai
(SOC > 3.5 µg m−3) including central and southern
Anhui, Zhejiang, and Fujian. The results from this study provide critical
information about the long-term trend of carbonaceous aerosol, in particular,
SOC, in one of the largest megacities in the world, and are helpful for
developing pollution control measures from a long-term planning perspective.
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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