Revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers with a focus on clumped-isotope measurements

Abstract

Abstract. In this work, we present a revision of an open-split-based dual-inlet system for elemental and isotope ratio mass spectrometers (IRMSs), which was developed by the division of Climate and Environmental Physics of the University of Bern 2 decades ago. Besides discussing the corresponding improvements we show that with this inlet system (NIS-II, New Inlet System II) external precisions can be achieved that are high enough to perform measurements of multiply substituted isotopologues (clumped isotopes) on pure gases. For clumped-isotope ratios 35/32 and 36/32 of oxygen, we achieved standard deviations of 3.4×10-9 and 4.9×10-9, respectively, that we calculated from 60 interval means (20 s integration) of pure-oxygen gas measurements. Moreover, we report various performance tests and show that delta values of various air components can be measured with precisions of the order of tens of per meg and higher with the NIS-II. In addition, we demonstrate that our new open-split-based dual-inlet system allows us to measure some of these delta values with significantly higher precisions than an NIS-I (precursor of the NIS-II) and conventional changeover-valve-based dual-inlet systems (tests performed with two dual-inlet systems built by Elementar and Thermo Finnigan). Especially, our measurements point out that our inlet system provides reliable results at short idle times (20 s) and that the corresponding data do not need to be corrected for non-linearity. However, the sample consumption of our open-split-based dual-inlet system is several orders of magnitude higher than that of changeover-valve-based ones (0.33 sccm versus 0.005 sccm; standard cubic centimetres per minute). Due to the successful preliminary tests regarding measurements of clumped-isotope ratios, we will continue our work in this area to perform clumped-isotope studies according to common practices.