Unexplored volatile organic compound emitted from petrochemical facilities: implications for ozone production and atmospheric chemistry
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Published:2021-08-02
Issue:15
Volume:21
Page:11505-11518
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ISSN:1680-7324
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Container-title:Atmospheric Chemistry and Physics
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language:en
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Short-container-title:Atmos. Chem. Phys.
Author:
Sarkar ChinmoyORCID, Wong Gracie, Mielnik Anne, Nagalingam Sanjeevi, Gross Nicole Jenna, Guenther Alex B.ORCID, Lee Taehyoung, Park TaehyunORCID, Ban Jihee, Kang Seokwon, Park Jin-Soo, Ahn Joonyoung, Kim DanbiORCID, Kim Hyunjae, Choi Jinsoo, Seo Beom-KeunORCID, Kim Jong-Ho, Kim Jeong-HoORCID, Park Soo Bog, Kim SaewungORCID
Abstract
Abstract. A compound was observed using airborne proton transfer reaction
time-of-flight mass spectrometry (PTR-TOF-MS) measurements in the emission plumes from the Daesan petrochemical facility in South Korea. The compound was detected at m/z 43.018 on the PTR-TOF-MS and was tentatively identified as ketene, a rarely measured reactive volatile organic compound (VOC). Estimated ketene mixing ratios as high as ∼ 50 ppb (parts per billion) were observed in the emission plumes. Emission rates of ketene from the facility were estimated using a horizontal advective flux approach and ranged from 84–316 kg h−1. These emission rates were compared to the emission rates of major known VOCs such as benzene, toluene, and acetaldehyde. Significant correlations (r2 > 0.7) of ketene with methanol, acetaldehyde, benzene, and toluene were observed for the peak emissions, indicating commonality of emission sources. The calculated average ketene OH reactivity for the emission plumes over Daesan ranged from 3.33–7.75 s−1, indicating the importance of the quantification of ketene to address missing OH reactivity in the polluted environment. The calculated average O3 production potential for ketene ranged from 2.98–6.91 ppb h−1. Our study suggests that ketene, or any possible VOC species detected at m/z 43.018, has the potential to significantly influence local photochemistry, and therefore, further studies focusing on the photooxidation and atmospheric fate of ketene through chamber studies are required to improve our current understanding of VOC OH reactivity and, hence, tropospheric O3 production.
Funder
National Institute of Environmental Research National Research Foundation of Korea
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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