On the effect of upwind emission controls on ozone in Sequoia National Park

Abstract

Abstract. Ozone (O3) air pollution in Sequoia National Park (SNP) is among the worst of any national park in the US. SNP is located on the western slope of the Sierra Nevada Mountains downwind of the San Joaquin Valley (SJV), which is home to numerous cities ranked in the top 10 most O3-polluted in the US. Here, we investigate the influence of emission controls in the SJV on O3 concentrations in SNP over a 12-year time period (2001–2012). We show that the export of nitrogen oxides (NOx) from the SJV has played a larger role in driving high O3 in SNP than transport of O3. As a result, O3 in SNP has been more responsive to NOx emission reductions than in the upwind SJV city of Visalia, and O3 concentrations have declined faster at a higher-elevation monitoring station in SNP than at a low-elevation site nearer to the SJV. We report O3 trends by various concentration metrics but do so separately for when environmental conditions are conducive to plant O3 uptake and for when high O3 is most common, which are time periods that occur at different times of day and year. We find that precursor emission controls have been less effective at reducing O3 concentrations in SNP in springtime, which is when plant O3 uptake in Sierra Nevada forests has been previously measured to be greatest. We discuss the implications of regulatory focus on high O3 days in SJV cities for O3 concentration trends and ecosystem impacts in SNP.