Highly time-resolved characterization of carbonaceous aerosols using a two-wavelength Sunset thermal–optical carbon analyzer
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Published:2021-06-03
Issue:6
Volume:14
Page:4053-4068
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ISSN:1867-8548
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Container-title:Atmospheric Measurement Techniques
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language:en
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Short-container-title:Atmos. Meas. Tech.
Author:
Bao Mengying, Zhang Yan-LinORCID, Cao Fang, Lin Yu-Chi, Wang YuhangORCID, Liu Xiaoyan, Zhang WenqiORCID, Fan Meiyi, Xie Feng, Cary Robert, Dixon Joshua, Zhou Lihua
Abstract
Abstract. Carbonaceous aerosols have great influence on the air quality, human health
and climate change. Except for organic carbon (OC) and elemental carbon (EC), brown carbon (BrC) mainly originates from biomass burning as a group of OC, with strong absorption from the visible to near-ultraviolet
wavelengths, and makes a considerable contribution to global warming. Large
numbers of studies have reported long-term observation of OC and EC
concentrations throughout the world, but studies of BrC based on long-term
observations are rather limited. In this study, we established a
two-wavelength method (658 and 405 nm) applied in the Sunset thermal–optical carbon analyzer. Based on a 1-year observation, we firstly investigated the characteristics, meteorological impact and transport process of OC and EC. Since BrC absorbs light at 405 nm more effectively than 658 nm, we defined the enhanced concentrations (dEC = EC405 nm − EC658 nm) and gave the possibility of providing an indicator of BrC. The receptor model and MODIS fire information were used to identify the presence of BrC aerosols. Our results showed that the carbonaceous aerosol concentrations were the highest in winter and lowest in summer. Traffic emission was an important source of carbonaceous aerosols in Nanjing. Receptor model results showed that strong local emissions were found for OC and EC; however, dEC was significantly affected by regional or long-range transport.
The dEC/OC and OC/EC ratios showed similar diurnal patterns, and the dEC/OC increased when the OC/EC ratios increased, indicating strong secondary
sources or biomass burning contributions to dEC. A total of two biomass burning events both in summer and winter were analyzed, and the results showed that the dEC concentrations were obviously higher on biomass burning days; however, no similar levels of the OC and EC concentrations were found both in biomass burning days and normal days in summer, suggesting that biomass burning emissions made a great contribution to dEC, and the sources of OC and EC were more complicated. Large number of open fire counts from the northwestern and southwestern areas of the study site were observed in winter and significantly contributed to OC, EC and dEC. In addition, the nearby Yangtze River Delta
area was one of the main potential source areas of dEC, suggesting that
anthropogenic emissions could also be important sources of dEC. The results
proved that dEC can be an indicator of BrC on biomass burning days. Our
modified two-wavelength instrument provided more information than the
traditional single-wavelength thermal–optical carbon analyzer and gave a new idea about the measurement of BrC; the application of dEC data needs to be further investigated.
Funder
National Natural Science Foundation of China
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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