SCIAMACHY lunar occultation water vapor measurements: retrieval and validation results

Abstract

Abstract. SCIAMACHY lunar occultation measurements have been used to derive vertical profiles of stratospheric water vapor for the Southern Hemisphere in the near infrared (NIR) spectral range of 1350–1420 nm. The focus of this study is to present the retrieval methodology including the sensitivity studies and optimizations for the implementation of the radiative transfer model on SCIAMACHY lunar occultation measurements. The study also includes the validation of the data product with the collocated measurements from two satellite occultation instruments and two instruments measuring in limb geometry. The SCIAMACHY lunar occultation water vapor measurements comparisons with the ACE-FTS instrument have shown an agreement of 5% on the average that is well within the reported biases of ACE in the stratosphere. The comparisons with HALOE have also shown good results where the agreement between the instruments is within 5%. The validations of the lunar occultation water vapor measurements with MLS instrument are exceptionally good varying between 1.5 to around 4%. The validations with MIPAS are in the range of 10%. A validated dataset of water vapor vertical distributions from SCIAMACHY lunar occultation measurements is expected to facilitate the understanding of physical and chemical processes in the southern mid-latitudes and the dynamical processes related to polar vortex.