Retrieval of stratospheric aerosol size distribution parameters using satellite solar occultation measurements at three wavelengths

Abstract

Abstract. In this work, a novel approach for the determination of the particle size distribution (PSD) parameters of stratospheric sulfate aerosols is presented. For this, ratios of extinction coefficients obtained from SAGE III/ISS (Stratospheric Aerosol and Gas Experiment III on the International Space Station) solar occultation measurements at 449, 756 and 1544 nm were used to retrieve the mode width and median radius of a size distribution assumed to be monomodal lognormal. The estimated errors at the peak of the stratospheric aerosol layer, on average, lie between 20 % and 25 % for the median radius and 5 % and 7 % for the mode width. The results are consistent in magnitude with other retrieval results from the literature, but a robust comparison is difficult, mainly because of differences in temporal and spatial coverage. Other quantities like number density and effective radius were also calculated. A major advantage of the described method over other retrieval techniques is that both the median radius and the mode width can be retrieved simultaneously, without having to assume one of them. This is possible due to the broad wavelength spectrum covered by the SAGE III/ISS measurements. Also, the presented method – being based on the analysis of three wavelengths – allows unique solutions for the retrieval of PSD parameters for almost all of the observed extinction spectra, which is not the case when using only two spectral channels. In addition, the extinction coefficients from SAGE III/ISS solar occultation measurements, on which the retrieval is based, are calculated without a priori assumptions about the PSD. For those reasons, the data produced with the presented retrieval technique may be a valuable contribution for a better understanding of the variability of stratospheric aerosol size distributions, e.g. after volcanic eruptions. While this study focuses on describing the retrieval method, and a future study will discuss the PSD parameter data set produced in depth, some exemplary results for background conditions in June 2017 are shown.