SIFT-MS optimization for atmospheric trace gas measurements at varying humidity

Abstract

Abstract. As direct real-time analysis techniques, selective ion flow tube mass spectrometry (SIFT-MS) and proton-transfer reaction mass spectrometry (PTR-MS) provide online measurement of volatile organic compounds (VOCs). Both techniques are widely used across several disciplines, e.g., atmospheric chemistry, food science, and medicine. However, the humidity of the sampled air greatly influences the quantified mixing ratio and must be accounted for. Here we present several improvements to a Voice200ultra SIFT-MS instrument to reduce background levels and enhance sensitivity. Increasing the sample gas flow to 125 sccm enables limits of detection (LODs) at the sub-parts-per-billion (sub-ppb) level, and the resulting humidity dependence is overcome by calibrating for humidity as well. A comparison with a PTR-QMS 500 showed detection limits of the PTR-MS still being an order of magnitude lower, whereas sensitivity was higher for SIFT-MS, and its calibration was still more robust against humidity. Thus, SIFT-MS is a suitable, lower-cost, and easy-to-use alternative for atmospheric trace gas measurements of more complex mixtures, even with isomers, at a varying humidity range.