Absolute, pressure-dependent validation of a calibration-free, airborne laser hygrometer transfer standard (SEALDH-II) from 5 to 1200 ppmv using a metrological humidity generator
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Published:2018-01-23
Issue:1
Volume:11
Page:459-471
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ISSN:1867-8548
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Container-title:Atmospheric Measurement Techniques
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language:en
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Short-container-title:Atmos. Meas. Tech.
Author:
Buchholz Bernhard, Ebert VolkerORCID
Abstract
Abstract. Highly accurate water vapor measurements are indispensable for understanding
a variety of scientific questions as well as industrial processes. While in
metrology water vapor concentrations can be defined, generated, and measured
with relative uncertainties in the single percentage range, field-deployable
airborne instruments deviate even under quasistatic laboratory conditions up
to 10–20 %. The novel SEALDH-II hygrometer, a calibration-free, tuneable
diode laser spectrometer, bridges this gap by implementing a new holistic
concept to achieve higher accuracy levels in the field. We present in this paper the absolute validation of
SEALDH-II at a traceable humidity generator during 23 days of permanent
operation at 15 different H2O mole fraction levels between 5 and
1200 ppmv. At each mole fraction level, we studied the pressure dependence
at six different gas pressures between 65 and 950 hPa. Further, we describe
the setup for this metrological validation, the challenges to overcome when
assessing water vapor measurements on a high accuracy level, and the
comparison results. With this validation, SEALDH-II is the first airborne,
metrologically validated humidity transfer standard which links several
scientific airborne and laboratory measurement campaigns to the international
metrological water vapor scale.
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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