PM₁ geochemical and mineralogical characterization using SEM-EDX to identify particle origin – Agri Valley pilot area (Basilicata, Southern Italy)

Abstract

Abstract. A PM1 geochemical and mineralogical study using Scanning Electron Microscopy (SEM) was performed on a pilot site in the Agri Valley which is close to the oil pre-treatment plant (C.O.V.A) of the Europe's largest on-shore hydrocarbon reservoir. The study identified PM1 geochemical and mineralogical characters in a period before, during and immediately after a burning torch flare event. The finer fraction (DFe < 0.7 μm) consisted mainly of secondary particles and soot. In the coarser fraction (DFe ≥ 0.7 μm), natural particles originating from crustal erosion and soot were abundant. Fine quartz particles and lower Al/Si ratios are markers for desert dust origin, proving that a Saharan dust episode which occurred during the observation period played a significant role in supplying geogenic aerosol components to the PM1. Largest amounts of ≥0.7 μm fraction particles observed on the day of flare event may be due to a greater supply of Saharan geogenic particles. Soot had been significantly increasing long before the flare event, suggesting that this increase is also related to other causes, although we cannot exclude a contribution from flaring. S-rich aerosol consisted mainly of mixed particles originating from deposition and heterogeneous nucleation of secondary sulfates on mineral dust. Only-S particles were identified in the ≥0.7 μm fraction following the flare event. These particles may be indicators of larger amounts of sulphur in the atmosphere.