On the improvement of NO₂ satellite retrievals – aerosol impact on the airmass factors

Abstract

Abstract. The accurate determination of nitrogen dioxide (NO2) tropospheric vertical columns from satellite measurements depends strongly on the airmass factor (AMF) used. A sensitivity study was performed with the radiative transfer model SCIATRAN to better understand the impact of aerosols on the calculation of NO2 AMFs. This influence was studied by varying the NO2 and aerosol vertical distributions, as well as physical and optical properties of the particles. In terms of aerosol definitions, the key factors for these calculations were identified as the relation between trace gas and aerosol vertical profiles, the optical depth of the aerosol layer, and single scattering albedo. In addition, surface albedo also has a large impact on the calculations. Overall it was found that particles mixed with the trace gas increases the measurements' sensitivity, but only when the aerosol is not very absorbing. The largest change, a factor of ~2 relative to the situation without aerosols, was found when a low layer of aerosol (600 m) was combined with a homogenous NO2 layer of 1.0 km. A layer of aerosol above the NO2 usually reduces the sensitivity of the satellite measurement. This situation is found mostly for runs with discrete elevated aerosol layers (representative for long-range transport) that can generate a decrease of the AMF values of up to 70%. The use of measured aerosol profiles and modelled NO2 resulted, generally, in much smaller changes of AMF relative to the pure Rayleigh case. Exceptions are some events of elevated layers with high aerosol optical depth that lead to a strong decrease of the AMF values. These results highlight the importance of aerosols in the retrieval of tropospheric NO2 columns from space and indicate the need for detailed information on aerosol properties and vertical distribution.