Factors controlling temporal variability of near-ground atmospheric ²²²Rn concentration over Central Europe

Abstract

Abstract. Specific activity of 222Rn in near-ground atmosphere has been measured quasi-continuously from January 2005 to December 2009 at two continental sites in Europe: Heidelberg (south-west Germany) and Krakow (southern Poland). Atmosphere was sampled at ca. 30 m and 20 m, respectively, above the local ground. Both stations were equipped with identical instrumentation. Regular observations of 222Rn were supplemented by measurements of surface fluxes of this gas in Krakow urban area, using two entirely different approaches. Atmospheric 222Rn concentrations varied at both sites in a wide range, from less than 2 Bq m−3 to approximately 40 Bq m−3 in Krakow and ca. 35 Bq m−3 in Heidelberg. Averaged over entire observation period, the 222Rn content in Krakow was approximately 30 % higher when compared to Heidelberg (5.86 ± 0.09 Bq −3 and 4.50 ± 0.07 Bq m−3, respectively). Distinct seasonality of 222Rn signal was visible in both presented time series, with higher values recorded generally during late summer and autumn. The surface 222Rn fluxes in Krakow also revealed a distinct seasonality, with broad maximum observed during summer and early autumn and minimum during the winter. Averaged over 5 yr observation period, the night-time surface 222Rn flux was equal 46.8 ± 2.4 Bq m−2 h−1. Although the atmospheric 222Rn levels at Heidelberg and Krakow appeared to be controlled primarily by local factors, it was possible to evaluate the "continental effect" in atmospheric 222Rn content between both sites, related to the gradual build-up of 222Rn concentration in the air masses travelling between Heidelberg and Krakow. The mean value of this load was equal 0.78 ± 0.12 Bq m−3. The measured minimum 222Rn concentrations at both sites and the difference between them was interpreted in the framework of a simple box model coupled with HYSPLIT analysis of air mass trajectories. Best fit of experimental and model data was obtained for the average 222Rn flux over the European continent equal 52 Bq m−2 h−1, the mean transport velocity of the air masses within convective mixed layer of PBL on their route from the Atlantic coast to Heidelberg and Krakow equal 3.5 m s−1, the mean rate constant of 222Rn removal across the top of PBL equal to the 222Rn decay constant and the mean height of the convective mixed layer height equal 1600 m.