Trends in Peroxyacetyl Nitrate (PAN) in the upper troposphere and lower stratosphere over Southern Asia during the summer monsoon season: regional impacts
Author:
Fadnavis S.ORCID, Schultz M. G.ORCID, Semeniuk K.ORCID, Mahajan A. S.ORCID, Pozzoli L.ORCID, Sonbawane S., Ghude S. D., Kiefer M., Eckert E.ORCID
Abstract
Abstract. We analyze temporal trends of Peroxyacetyl Nitrate (PAN) retrievals from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) during 2002–2011 in the altitude range 8–23 km over the Asian summer monsoon (ASM) region. The greatest enhancements of PAN mixing ratios in the upper troposphere and lower stratosphere (UTLS) are seen during the summer monsoon season from June to September. During the monsoon season, the mole fractions of PAN show statistically significant (at 2 sigma level) positive trends from 0.2 ± 0.05 to 4.6 ± 3.1 ppt year−1 (except between 12–14 km) which is higher than the annual mean trends of 0.1 ± 0.05 to 2.7 ± 0.8 ppt year−1. These rising concentrations point to increasing NOx (=NO+NO2) and volatile organic compound (VOC) emissions from developing nations in Asia, notably India and China. We analyze the influence of monsoon convection on the distribution of PAN in UTLS with simulations using the global chemistry-climate model ECHAM5-HAMMOZ. During the monsoon, transport into the UTLS over the Asian region primarily occurs from two convective zones, one extending from the Bay of Bengal to the South China Sea and the other over the southern flank of the Himalayas. India and China are NOx limited regions, and thus we use the model to evaluate the contributions from enhanced NOx emissions to the changes in PAN, HNO3 and O3 concentrations in the UTLS. From a set of sensitivity experiments with emission changes in particular regions it can be concluded that Chinese emissions have a greater impact on the concentrations of these species than Indian emissions. NOx emissions increases over India are about half of those over China.
Publisher
Copernicus GmbH
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