Stratospheric and mesospheric HO<sub>2</sub> observations from the Aura Microwave Limb Sounder
Author:
Millán L., Wang S.ORCID, Livesey N., Kinnison D., Sagawa H.ORCID, Kasai Y.
Abstract
Abstract. This study introduces stratospheric and mesospheric hydroperoxyl radical (HO2) estimates from the Aura Microwave Limb Sounder (MLS) using an offline retrieval (i.e. run separately from the standard MLS algorithm). This new dataset provides two daily zonal averages, one during daytime and one during nighttime, with a varying vertical resolution from about 4 km at 10 hPa to around 14 km at 0.0032 hPa. A description of the methodology and an error analysis are presented. Comparisons against the Whole Atmosphere Community Climate Model (WACCM), the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) and the Far Infrared Spectrometer (FIRS-2) measurements, as well as, photochemical simulations demonstrate the robustness of the retrieval and indicate that the retrieval is sensitive enough to detect mesospheric HO2 layers during both day and night. This new dataset is the first long-term HO2 stratospheric and mesospheric satellite record and it provides needed constraints to help resolve the O3 deficit problem and the "HOx dilemma".
Publisher
Copernicus GmbH
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