Source apportionment of black carbon and combustion-related CO2 for the determination of source-specific emission factors
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Published:2023-01-12
Issue:1
Volume:16
Page:135-152
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ISSN:1867-8548
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Container-title:Atmospheric Measurement Techniques
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language:en
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Short-container-title:Atmos. Meas. Tech.
Author:
Alfoldy Balint, Gregorič AstaORCID, Ivančič Matic, Ježek Irena, Rigler MartinORCID
Abstract
Abstract. Black carbon (BC) aerosol typically has two major sources in the urban environment: traffic and domestic biomass burning, which has a significant contribution to urban air pollution during the heating season.
Traffic emissions have been widely studied by both laboratory experiments
(individual vehicle emission) and real-world measurement campaigns (fleet
emission). However, emission information from biomass burning is limited,
especially an insufficiency of experimental results from real-world studies.
In this work, the black carbon burden in the urban atmosphere was
apportioned to fossil fuel (FF) and biomass burning (BB) related components
using the Aethalometer source apportionment model. Applying the BC source
apportionment information, the combustion-related CO2 was apportioned
by multilinear regression analysis, supposing that both CO2 components should be correlated with their corresponding BC component. The combination
of the Aethalometer model with the multilinear regression analysis (AM-MLR) provided the source-specific emission ratios (ERs) as the slopes of the
corresponding BC–CO2 regressions. Based on the ER values, the source-specific emission factors (EFs) were determined using the carbon
content of the corresponding fuel. The analysis was carried out on a 3-month-long BC and CO2 dataset collected at three monitoring locations in Ljubljana, Slovenia, between December 2019 and March 2020. The measured mean site-specific concentration values were in the 3560–4830 ng m−3 and 458–472 ppm ranges for BC and CO2, respectively. The determined average EFs for BC were 0.39 and 0.16 g(kg fuel)−1 for traffic and
biomass burning, respectively. It was also concluded that the
traffic-related BC component dominates the black carbon concentration
(55 %–64 % depending on the location), while heating has the major share in
the combustion-related CO2 (53 %–62 % depending on the location). The
method gave essential information on the source-specific emission factors of
BC and CO2, enabling better characterization of urban anthropogenic
emissions and the respective measures that may change the anthropogenic
emission fingerprint.
Funder
Ministrstvo za Gospodarski Razvoj in Tehnologijo Javna Agencija za Raziskovalno Dejavnost RS
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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