Preparation of high-temperature gels for enhanced oil recovery using methyl etherized melamine-formaldehyde resin

Abstract

Polymer gels are the most commonly used materials in the petroleum industry for reservoir conformance control and resolving excessive water production problems. In this study, high-temperature gels were prepared with HPAM or AM/AMPS as the gel-forming agent, methyl etherified melamineformaldehyde resin (MEMFR) as the crosslinker, and nano-silica as the stabilizer, and their properties were evaluated. The results showed that HPAM-MEMFR gels were unstable at 110°C in a brine of 20665 mg/L. AM/AMPS-MEMFR gels are stable at 110°C, with gelation time ranging from 15 h to 92 h and storage modulus ranging from 3.6 Pa to 50 Pa. AM/AMPS-MEMFR gel has less than 10% dehydration after aging at 110°C for 90 days, almost no shrinkage in volume, and a significant increase in strength, making it suitable as a gel material for enhanced oil recovery.