Influence of Au0 metallic particles on NIR laser emission of Yb3+ ions in Li2O−HfO2−SiO2 glass ceramic

Abstract

This study consists of the synthesis, characterization, and analysis of photoluminescence (PL) spectra for Li2O−HfO2−SiO2−Yb2O3 glass ceramics sensitized with small amounts of Au2O3. Using the results of XRD and X-ray photoelectron spectroscopy (XPS) studies indicated a progressive reduction of Au3+ ions into Au0 metallic particles (MPs) with increase of Au2O3 content. Investigations into the infrared spectra highlighted a growing concentration of induced defects in the samples due to the increased proportion of Au0 MPs. Optical absorption (OA) spectra exhibited a distinct band attributed to the 2F7/2 → 2F5/2 transition of Yb3+ within wavelength range of 800–980 nm. Furthermore, a wide absorption band linked to the surface plasmon resonance (SPR) of Au0 MPs was identified in the visible region. PL spectra, recorded at λexc = 450 nm, revealed a band between 980 to 1025 nm, associated with the 2F5/2 → 2F7/2 transition of Yb3+ ions. Another emission band was observed due to the sp → d transition of Au0 MPs within the visible region. Observed enhanced PL emission from Yb3+ ions in the NIR range was ascribed to the energy transfer from Au0 MPs to Yb3+ ions. Ultimately, it was deduced that Au0 MPs played a pivotal role in enhancing the PL output of Yb3+ ions in the Li2O−HfO2−SiO2 glass ceramic. Thus, glass ceramics incorporating an optimal concentration of Au2O3 hold significant potential as materials for NIR lasers.