Low-temperature dynamics in a dye-doped polymer: correspondence between the data obtained by photon echo and single molecule spectroscopy

Abstract

Low temperature dynamics (tunneling and vibrational relaxation) in doped polyisobutylene film has been reinvestigated using 2-pulse incoherent photon echo (2IPE) and compared with single-molecule spectroscopy (SMS) data. It has been shown that in a very wide range of low temperatures the 2IPE gives optical dephasing times which correspond to the narrowest zero-phonon lines of single dye molecules.