Abstract
Manganese sulfate is an important base manganese salt; nearly 80% of the world's manganese products are produced using manganese sulfate or manganese sulfate solution. Furthermore, manganese sulfate has many applications in industry and agriculture; thus, manganese sulfate solution impurity removal technology is important. This study aims to remove impurities from manganese sulfate solution-using complex low-grade manganese ore and manganese-rich fumes after pressure acid leaching to obtain a manganese sulfate solution, which is then purified through iron removal by oxidation neutralization; finally, the purified liquid is treated using extraction-back-extraction. We investigated the effects of various extraction parameters on the extraction rate of manganese, as well as the effects of various back-extraction parameters on the manganese back-extraction rate and manganese ion concentration in the back-extraction solution, and studied the extraction-back-extraction process. We found that the extraction and back-extraction rates of manganese could reach 95% and 96.9%, respectively, under optimal conditions..
Publisher
Trans Tech Publications, Ltd.
Reference23 articles.
1. H.Y. Xie (2013) Study on the pressurized acid leaching purification extraction technology of complex low-grade manganese ore and manganese containing dust. Dissertation, Kunming University of Science and Technology.
2. K. Wang, Q.W. Zhang, H.M. Hu, Y.C. Liu (2019) Efficient removal of iron (II) from manganese sulfate solution by using mechanically activated CaCO3. Hydrometallurgy 188: 169-173
3. Y.S. Wang, L. Zeng, G.Q. Zhang, W.J. Guan, Z. Sun, D. Zhang, J.L. Qing (2019) A novel process on separation of manganese from calcium and magnesium using synergistic solvent extraction system. Hydrometallurgy 185:55-60
4. T. Gigla, S. Djemal, K. Nana, L. Tinatin, G. David, B. Levan, S. Suladze, K. Izolda (2019) Novel hydro-electrometallurgical technology for simultaneous production of manganese metal, electrolytic manganese dioxide, and manganese sulfate monohydrate. Hydrometallurgy 186: 260-268
5. X.P. Yu, J.J. Cui, C.L. Liu, F. Yuan, Y.F. Guo, T.L. Deng (2021) Separation of magnesium from high Mg/Li ratio brine by extraction with an organic system containing ionic liquid. Chemical Engineering Science 229: 116019