Preparation of Ruthenium Hollow Spheres as Catalysts for Selective Hydrogenation of Benzene to Cyclohexene

Author:

Rao Hou Dong1,Zhang Dong Yang1,Li Jing Rui1,Zhang Ling1,Cheng Wei1

Affiliation:

1. Luoyang Ship Material Research Institute

Abstract

In this paper, a simple and effective method was used to synthesize monodisperse metal Ruthenium nanospheres (Ru-HNSs), and the silicon dioxide (SiO2) nanospheres synthesized by Stober method were used as hard templates. The surface of SiO2 was double modified by γ-aminopropyltriethoxysilane (KH550) and salicylaldehyde, so that Ru3+ grew uniformly on the surface of modified SiO2 and reduced to form a stable and durable layer of Ru metal. Then the hard template SiO2 was corroded by chemical etching to obtain Ru-HNSs hollow spheres. The results show that the diameter of SiO2 microspheres was about 300nm, the wall thickness of Ru-HNSs was about 3nm, and the diameter was about 100nm.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference15 articles.

1. Cao, H. E., Zhu, B. R., Yang, Y. F., Xu, L., Yu, L., Xu, Q. Recent advances on controllable and selective catalytic oxidation of cyclohexene. Chinese Journal of Catalysis, 39(5)899-907, (2018).

2. Huang, Z. X., Liu, Z. Y., Wu, Y. M., Liu, S. C. Selective Hydrogenation of Benzene to Cyclohexene by a Novel Ru-Zn Catalyst. Journal of Molecular Catalysis, 20(3), (2006).

3. Dong, S., Fang, C. X., Wang, Y. T. Research progress on catalysts for selective hydrogenation of benzene to cyclohexene. Chemical Industry and Engineering Progress, 30(7), (2011).

4. Yang, X. L., Guo, Y. Q., Zhang, Z. J., Liu, S. C. Study on Ru-Co-B/ZrO2 catalyst for selective hydrogenation of benzene to cyclohexene. Chemical Research and Application, 15(5)664-665, 672, (2003).

5. Wang, J. Q., Xie, S. H., Chen, H. Y., Hu, J. G., Fan, K. N. The Preparation and Catalytic Behavior ofRu/ZrO2·xH2O in Benzene Selective Hydrogenation. Journal of Fudan University (Natural Science Edition), 41(4):429-432, 438, (2002).

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3