Preparation, Structure, and Photophysical Behavior of Europium (III) Complexes of Decyl Alanine and Lauryl Alanine

Author:

Han Jakang1,Gerile Naren1,Zhang Ying1,Shi Yi Feng1,Altan Bolag1,Tegus O.1

Affiliation:

1. Inner Mongolia Normal University

Abstract

Two Ligands (H (dec-ala) and H (dod-ala)) prepared from decyl chloride, lauroyl chloride, and amino acids (DL-alanine), reacted with Europium chloride in methanol solution, leading to two Europium (III) complexes of Eu (dec-ala)3 and Eu (dod-ala)3.Elemental analysis, NMR, and FT-IR spectra proved the elemental content, structural information of the synthesized Europium (III) complexes. The light absorption and luminescence properties were characterized by UV-vis and PL spectra analysis. Both complexes have excellent absorption capacity in the range of 200 nm-300 nm. The ideal excitation wavelengths of these complexes are at 394 nm, and the principal emission peaks are at 590 nm, 610 nm, 650 nm, and 698 nm, which correspond to 5D07F1, 5D07F2, 5D07F3, 5D07F4, respectively.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference20 articles.

1. Alexander K A, Dmitry M L, Tatyana V M, et al. Rare-earth dichloro and bis(alkyl) complexes supported by bulky amino-imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization, Dalton Trans. 25 (2013) 9211-9125.

2. Song S H, Sun H J, Wang M. Effect of rare earth cerium on brittleness of simulate welding heat-affected zones in a reactor pressure vessel steel, J. Rare Earths. 11 (2015) 1204-1211.

3. Li Y T, Hao J, Gao C H, et al. Structure and luminescence properties of samarium (Ⅲ) and europium(Ⅲ) binuclear organic complexes, Modern Chemical Industry. 41 (2021) 133-137+143.

4. Wang Y J. Synthesis, Structures and Luminescent/Magnetic Properties of Dinuclear Rare earth Complexes, Tianjin University. (2020)

5. Li R Q. Fabrication and Characterization for Novel Luminescent Aggregates Based on Lanthanide Complexes and Ionic Liquids, Shandong University. (2020)

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3