Affiliation:
1. Ural Federal University
Abstract
This work investigated the surface tension and kinematic viscosity of the multicomponent Fe73.5Cu1Nb3Si13.5B9 melt. A relationship was found between surface tension and kinematic viscosity, which manifests itself in a synchronous change in these quantities at temperatures of 1600 and 1780 K. In the temperature range 1600–1780 K, there is a sharp increase in surface tension upon heating and the same decrease upon cooling. The increase in surface tension during heating was explained by the appearance of a large number of free Nb atoms as a result of the dissolution of the residual crystalline phase in the mushy zone, and their diffusion to the melt surface. The drop in the surface tension on cooling below 1780 K is associated with the liquid–liquid structure transition (LLST), which stimulates the outflow of Nb atoms from the surface in order to form new stable clusters. The LLST manifests itself in a change in the activation energy of a viscous flow, which is higher in the high-temperature region and corresponds to the motion of larger clusters with a length scale of about 1 nm.
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Reference21 articles.
1. B.A. Baum, Metal liquids, Nauka, Moscow, (1979).
2. L. Goumiri, J.C. Joud, Average atomic order effect – prediction of bulk and surface properties of liquid metallic systems, Surf. Sci. 138 (1984) 524–548.
3. O,G. Shpyrko, R. Streitel V.S.K. Balagurusamy, A.Y. Grigoriev, M. Deutsch, B.M. Ocko, M. Meron, B. Lin, P.S. Pershan, Surface crystallization in a liquid AuSi alloy, Science 313 (2006) 77–80.
4. S.I. Popel, Surface phenomena in melts, Metallurgiya, Moscow, (1994).
5. I. Egry, E. Ricci, R. Novakovic, S. Ozawa, Surface tension of liquids metals and alloys – recent developments, Adv. Colloid Interface Sci. 159 (2010) 198–212.